白光LED用Ca_2SiO_4:Ce~(3+)/Eu~(2+)荧光粉的合成及发光特性Synthesis and Luminescent Properties Phosphor Ca_2SiO_4: Ce~(3+)/Eu~(2+) for White LED
周晨露;陈家玉;姚合宝;
摘要(Abstract):
采用高温固相法合成了蓝色Ca_2SiO_4:Ce~(3+)以及蓝绿双色Ca_2SiO_4:Ce~(3+),Eu~(2+)荧光粉,通过粉末X射线衍射(XRD)和荧光光谱对其结构和光学性能进行了研究。确定了Ce~(3+)离子的最佳掺杂浓度、浓度猝灭机制、格位分布及热稳定性,并探讨了Ce~(3+)→Eu~(2+)的能量传递过程和能量传递效率。结果表明,此荧光粉在近紫外波段有强的宽带吸收,可以被InGaN芯片产生的紫外光有效激发;其发光颜色可以从蓝(429nm)到绿(505 nm)实现可调,作为蓝色和绿色荧光粉用于白光LED器件中。
关键词(KeyWords): 正硅酸盐;LED;荧光粉;能量传递;热稳定性;稀土
基金项目(Foundation): 陕西省教育厅科研计划项目(16JK2216)资助
作者(Author): 周晨露;陈家玉;姚合宝;
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DOI:
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