钙钛矿锰氧化物La_(0.875)Eu_(0.025)Sr_(0.1)MnO_3的磁性和磁卡效应研究Magnetic Properties and Magnetic Entropy Change of Perovskite Manganites La_(0.875)Eu_(0.025)Sr_(0.1)MnO_3
金香;孙晓东;曹凤泽;田野;云慧琴;鲁毅;赵建军;
摘要(Abstract):
多晶样品La_(0.875)Eu_(0.025)Sr_(0.1)MnO_3用传统固相反应法制备得到。X射线衍射仪(XRD)表明样品为纯相。通过测量磁化强度随温度的变化曲线(M-T)、不同温度下磁化强度随磁场的变化曲线(M-H)研究了该多晶样品的磁性及磁卡效应。研究发现:样品在低温部分表现出团簇自旋玻璃的特征,在15~125 K温度范围内表现为铁磁特征;在125~350 K温度范围内表现出预成型团簇相的特征;在350 K以上表现出纯顺磁特征。在居里温度T_C≈119 K附近,系统发生了二级相变而且出现较大的磁熵变值,样品在7 T外加磁场下的最大磁熵变绝对值为2.83J·K~(-1)·kg~(-1),磁制冷效率为427.53 J·kg~(-1)。因此,该样品具有在高温区实现磁制冷的潜能。
关键词(KeyWords): 钙钛矿;磁性;磁熵变;相变;稀土
基金项目(Foundation): 国家自然科学基金项目(11164019,51562032,61565013);; 内蒙古自然科学基金项目(2015MS0109);; 内蒙古高校科研重点项目基金项目(NJZZ11166,NJZY16237,NJZY12202);; 包头市科技局项目(2015Z2011);; 包头师范学院青年科学研究基金项目(BSYKJ2014-22)资助
作者(Author): 金香;孙晓东;曹凤泽;田野;云慧琴;鲁毅;赵建军;
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参考文献(References):
- [1] Sun Y,Tong W,Zhang Y H. Large magnetic entropy change above 300 K in La0. 67Sr0. 33Mn0. 9Cr0. 1O3[J]. J.Magn. Magn. Mater.,2001,232(3):205.
- [2] Lu Y,Di N L,Wang G J,Li Q A,Cheng Z H. Lowfield-induced magnetic entropy change in single-crystal Nd0. 47Sr0. 53MnO3[J]. J. Phys. Condens. Mat.,2004,16(16):243.
- [3] Phan M H,Yu S C. Review of the magnetocaloric effect in manganite materials[J]. J. Magn. Magn. Mater.,2007,308(2):325.
- [4]陈湘,陈云贵,唐永柏,肖定全.一级相变磁制冷材料La Fe11. 6Si1. 4合金的磁相变特性系统分析[J].中国稀土学报,2015,33(3):307.Chen X,Chen Y G,Tang Y B,Xiao D Q. System analysis of magnetic phase transition characteristics in the first-order magnetic refrigeration material of La Fe11. 6Si1. 4alloys[J]. Journal of the Chinese Society of Rare Earths,2015,33(3):307.
- [5]龙毅,付松,叶荣昌.磁制冷材料实用化研究进展[J].中国稀土学报,2012,30(6):641.Long Y,Fu S,Ye R C. Process of magnetic refrigeration materials for application[J]. Journal of the Chinese Society of Rare Earths,2012,30(6):641.
- [6]龙毅,付松.磁制冷材料中一级磁相变的研究进展[J].中国材料进展,2011,30(9):21.Long Y,Fu S. Progress toward first-order magnetic transition in magnetic refrigerants[J]. Materials China,2011,30(9):21.
- [7]万素磊,何利民,向俊尤,王志国,邢茹,张雪峰,鲁毅,赵建军.钙钛矿型锰氧化物(La0. 8Eu0. 2)4/3Sr5/3Mn2O7的磁性和电性研究[J].物理学报,2014(23):328.Wan S L,He L M,Xiang J Y,Wang Z G,Xin R,Zhang X F,Lu Y,Zhao J J. Magnetic and transport properties of bilayeredperovskitemanganites(La0. 8Eu0. 2)4/3Sr5/3Mn2O7[J]. Acta Phys. Sin.,2014,63(23):328.
- [8] Abramovich A I,Michurin A V,Gorbenko O Y,Kaul A R. Giant magnetocaloric effect near the curie temperature in the Sm0. 6Sr0. 4MnO3manganite[J]. Phys. Solid State,2001,43(4):715.
- [9]王洪金,郑玲,邢茹,赵建军,鲁毅,成昭华.层状钙钛矿锰氧化物La1. 3-xGdxSr1. 7Mn2O7(x=0,0. 05)的磁性和电性研究[J].中国科学物理学力学天文学,2012,42(7):695.Wang H J,Zheng L,Xing R,Zhao J J,Lu Y,Cheng Z H. Magnetic and transport properties of bilayered perovskite manganites La1. 3-xGdxSr1. 7Mn2O7(x=0,0. 05)[J]. Scientia Sinica Physica Mechanica&Astronomica,2012,42(7):695.
- [10] Joshi J P,Gupta R,Sood A K,Bhat S V,Raju A R,Rao C N R. Temperature-dependent electron paramagnetic resonance studies of charge-ordered Nd0. 5Ca0. 5MnO3[J]. Phys. Rev. B,2011,65:024410.
- [11] He C,Torija M A,Wu J,Lynn J W,Zheng H,Mitchell J F. Non-Griffiths-like clustered phase above the Curie temperature of the doped perovskite cobaltite La1-x SrxCo O3[J]. Phys. Rev. B,2007,76(1):014401.
- [12] Huang W G,Zhang X Q,Li G K,Li Q A,Cheng Z H.Fe-doping induced Griffiths-like phase in La0. 7Ba0. 3Co O3[J]. Chin. Phys. B,2009,18(11):5034.
- [13] Zhou S M,Li Y,Guo Y Q,Zhao J Y,Cai X,Shi L.Observation of a Griffiths-like phase in Ca-doped cobaltites[J]. J. Appl. Phys.,2013,114:163903.
- [14] Gschneidner K. Recent developments in magnetocaloric materials[J]. Rep. Prog. Phys., 2005, 68(6):1479.
- [15] Mira J,Rivas J. First order magnetic phase transitions and colossal magnetoresistance:joining manganese perovskites and MnAs[J]. Mod. Phys. Lett. B,2004,18(15):725.
- [16] Gschneidnerjr K A,Pecharsky V K,Tsokol A O. Recent developments in magnetocaloric materials[J].Rep. Prog. Phys.,2005,68(6):1479.