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Journal of Rare Earths
Administrated by CAST
Sponsored by CSRE and GRINM
Published by Elsevier B.V.
Editor-in-Chief: XU Guang xian
Journal of Rare Earths
(monthly, Since 1990)
ISSN 1002-0721 CODEN: JREAE6
Journal of the Chinese Society of Rare Earths
(Bimonthly, Since 1983)
ISSN 1000-4343 CODEN: ZXXUE5
 
Journal of Rare Earths Issue
Journal of Rare Earths 2008 Year Vol.26 NO.1 Page: 40-43
Synthesis of colloidal LaF3: 0.04Yb3+, 0.01Er3+ nanocrystals with green upconversion luminescence
WANG Yan (王 艳)1, 2, QIN Weiping (秦伟平)1, 3, ZHANG Jisen (张继森)1, CAO Chunyan (曹春燕)1, 2, ZHANG Jishuang (张继双)1, 2, JIN Ye (金 叶)1, 2
(1. Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China; 3. State Key Laboratory of Integrated Optoelectronics, College of Electronic Science & Engineering, Jilin University, Changchun 130012, China)
Abstract:

A synthesis of LaF3:0.04Yb3+,0.01Er3+ nanocrystals with oleic acid as a capping ligand was presented. The X-Ray Diffraction (XRD) pattern indicated that the power was a single hexagonal phase. Transmission Electron Microscopy (TEM) demonstrated that the average size of the nanocrystals was less than 10 nm, with a narrow size distribution. The nanocrystals were dispersible in nonpolar solvents and form a fully transparent colloidal solution, and the solution was stable for several months without any aggregates. The Yb3+-Er3+ codoped nanocrystal colloidal solution exhibited a bright green upconversion fluorescence under 980 nm excitation from a diode laser. The nanocrystals were potentially applicable in biolabeling and bioimaging.

Key word:upconversion luminescence; colloidal; LaF3:0.04Yb3+,0.01Er3+; nanocrystals; rare earths
    
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